Sounds like that tree is a popular one among the buck crowd. We have hundreds of black walnut of around that age but the bucks leave them alone. Here, their preference is for the young hybrid poplar and
black locust saplings. Luckily, both of those coppice well and always spring back with vigor.
Anything that gets in the way of their antlers will discourage them. I've used black plastic drainage tile, split lengthwise as a protector. Leaving lower branches on or letting weeds grow tall around the tree also discourages them. I've had this idea about hanging a piece of rope on the trees that size to see if that would discourage it. That is on my to do list for this fall, selectively, to see if it makes a difference.
Terry Calhoun
Bratsholme Farm
https://www.facebook.com/BratsholmeFarm
20 acres, previously farmed with tree lines, 36' of elevation change over 1,300 feet of south facing slope, 7,000+ trees planted so far in previously tilled acres at a density of ~500 per acre.