What climate zone and soil type are you working with? I'd like to grow figs but they're iffy to grow here, if in a sheltered spot they might be fine or they might freeze to death. But most people aren't going to pick and eat something they're not already used to eating raw. A variety of
rose which has been bred for scent, lilac bushes, mint, anise might be good. Dwarf citrus if you're somewhere warm
enough... people seem to be pretty brave about eating oranges. People used to look at me sideways when I picked and ate mulberries walking to/from home in college. Tomatoes have already been mentioned, cherry tomatoes in particular may appeal to passers by. Ground cherry/chinese lantern is already accepted as an ornamental.