I think it's a brilliant
reuse of materials. I've done this with double-pane glass and it works.
Drawbacks?
Single pane glass lets the heat in, but it also lets the heat out. Be prepared to throw on a tarp or cover in frosty conditions.
Old windows may well have layers of lead paint. Not the end of the world, but take steps to keep it from flaking off into your soil.
As you set it up, hinge it so it's easy to
water and to ventilate in a serious way during the day. You don't want to fry your tender young plants.
In broader use, I have seen "open air" setups where old windows are used to create a microclimate. It's sort like the walls of a
greenhouse with no roof, with a door and everything. And yet you get the rain coming in with zero effort.
My 2c. Hope this is useful.