posted 6 months ago
Insulation in heated cob (hot enough to burn out the organic filler) comes from well distributed small pores. Straw would be one of the best for this, as where it does not get hot enough to char, it is structural, and where it chars, it leaves hollow tubes of space which give insulation. The more straw, the more insulation, as long as the fired cob still holds together. Dried grass leaves flat thin voids, and would be less effective as insulation. It does make nice workable cob for finished surfaces, as the fine grass allows quite a smooth surface.
Sawdust is another common filler for insulating cob. It would give little strength, but in higher proportions could make a well insulating material.
Testing for numerical insulating value is likely beyond the capacity of any home workshop; I would make up panels say a foot square by a few inches thick (all identically sized), and put them equally spaced around a uniform heat source, and see how long each sample takes to feel warm or hot. This will give you a useful comparison between your available materials.