Neat question!
Grab a
coffee... this might take a while.
Different fibres react differently to different temperatures... so, short
answer - it depends on what you are boiling.
Linen for example is the perfect candidate for boiling. Not only does it help to whiten linen, especially new linen, but it softens it as well. I don't recommend this with your heirloom great grandmother's linen, but for everyday linen, boiling can do the world of good. Because the linen fibres are quite smooth, the boiling water helps to release most of the dirt particles. When boiling linen it helps to add a pinch of washing soda or baking soda to the water for longer lasting linen.
Synthetics ... there are so many different kinds, but I'm balling them up into one big category because I'm not much of a fan. I'm including some of the new rayons like
bamboo (not silk, RAYON - silk is just a marketing ploy),
soy rayon,
sea cell, and the usual synthetic suspects like
viscose and
polyester. Many of these have a lower melting point than natural fibres. I don't imagine that boiling the cloth will do any good, in fact, it might melt the fibres and help the dirt to permanently attach to the cloth. It would likely destroy any
elastic material in the cloth as well, like stretchy waste bands - this falls into the synthetic category. Plastic, bone, horn and possible shell buttons will also be an issue.
Cotton is another one that dosen't mind boiling. Because of the structure of the fibre, it will probably shrink the cloth a fair amount, the same way as going into a steamy room automatically takes 4 inches off my hair. The individual fibres go from straight-ish to curly. Kind of neat with hair. Fine with a towel. Not so good for a shirt. You may need to 'block' it as it drys - which is to stretch it to the shape and size you need, then keep it there somehow. As for getting dirt off, boiling water and cotton work okay. Over time, it would weaken the cotton fibres, or at least that's the common opinion in textile
books. My thoughts are my pudding cloth get's boiled loads and it shows no sign of weakening.
Wool and animal fibres are a different story.
Hot water yes, but boiling will most likely result in felting. The motion of the boiling water causes the fibres to rub together, which when wet is how we create felt.
Here endith the theory part of the post.
In real life, I think it's worth a go. Especially with cotton and linen fabrics. It may work or it may not. It depends a lot on how the fabric was constructed - every element of how it was constructed from method of spinning the
thread, through to how the seams were sewn... and what the seams were sewn with (synthetic thread that will melt?). Maybe start with clothes that you don't mind loosing. Give it a try and let us know how it goes.