i think you've got the right idea with coppicing your trees. the leaves will indeed rot down quickly and provide an excellent mulch. small wood will rot quick
enough, as mentioned, and larger pieces can be used for additional benefits like animal
shelters, arbors, and general habitat. i have a buddy that makes her own tool handles from black locust. it's resistance to rot, along with a rubbing of black walnut hull oil (apologies i don't know the processes), and it's density makes it a decent resource. i don't have any experience with this personally, but for the sake of experimentation. another suggestion a friend mentioned (and i think i read it somewhere) was to cover plants you wanted to protect with black locust for its thorns.
before going after thinning the whole space i'll pass on something i wish someone told me. don't create gaps you can't fill. an opening invites a new group of species if it isn't prepared and filled with what you want to grow there. i learned to pick patches of varying sizes based on site conditions (sun, wind protection, microclimate, access to house, access for mechanical equipment). in pennsylvania a poorly planned gap will give you barberry and huckleberry thickets that take at least a couple seasons to struggle with. grow for seed and division. i've bought new species by seed and seedling and done my best to propagate from these. aside from the financial benefit there is the more important experience of protracted observation and learning from the
land. on top of that you end up cultivating the plants that do well with your conditions (juglone and nitrogen-rich). one small gap patch established will give you several more the following year and so on.
another wonderful thing about black locust is its relatively open crown if given space. i would look to coppice leggy trees and keep open ones to cultivated your partial shade varieties. when opening a patch i consider the middle, the edge, and 5 to 20 meters into the understory. i'd say when creating a new clearing i spend the majority of the work and hand planting on the edge. i've learned to focus on shade plants more because they are harder spaces to establish. as you open more light into gaps from previous seasons the shade plants will move themselves, effectively filling the increasing perimeter for you. i'm by no means an expert on this, just a dabbler a few years deep in trial-and-error, but i hope my perspective can be of some use.