Some small amount of heat may be produced - but comparing brown leaves to a hot manure heap is much like comparing a candle to a bonfire.
A pile of leaves is a very effective insulator as well, so often will feel warmer and drier than the surroundings. You can make a really really warm and comfortable winter survival
shelter from twigs and leaves heaped up. Do a search for 'debris hit' to see what I mean.
What appears to matter though is the rate at which heat is produced, rather than the temperature that can be reached. Similar conversations happen with
solar power - you can make an insulated box that gets hot enough to warp and melt plastic but is still lousy because the rate of
energy gain is too small.
By all means try it but my own experiences suggest it is unlikely to be successful. After all - farmers and market gardeners have been using these techniques for generations and have always advocated tonnes of the freshest horse manure they can get.