I've been living in high desert in solely passive
solar heated buildings for 20 years. But our attached greenhouses are removed for the summer, and I'm a big fan of that. Overheating in summer is a real issue with a permanently attached
greenhouse. But an attached greenhouse is wonderful in winter.
I have some opinions on the following materials that we have used:
1) Flexible UV resistant plastic film. This is available at a subsidised price here because the govt supports the production of vegetables. We've had two types. They tend to last about 5 - 8 years if we attach and detach them, and actually longer if left in place with a firmer attachment system. They flap in the wind, which can be annoying or even alarming, and one flew off in an unusual gust, taking its wooden frame with it and breaking some windows on the building above (after having sat in place for about 10 years). But generally this material is the one we use on all our removable greenhouses. After the corners rip and it's no good for another winter on the building, it makes a very useful tarp for a few more years.
2) Single UV-resistant polycarbonate or single glass. I like single glazing best for places where you want to see out the window. We use glass for our windows, and polycarbonate for doors and skylights. Personally i like single rather than double or multiple for the reasons below. I like insulated curtains on winter nights, and clean single glazing during the days.
3) Five-walled polycarbonate. The advantage of this is obviously the increased insulation. We have it on some of our skylights. The disadvantage is that it's hard to seal the ends perfectly airtight, so it starts to get clouded up with dust that blows in during gusts, or bugs that get in.
4) Homemade double glass. Similar issues. Dust gets in and sticks to the humidity that also gets in, and anyway glass does eventually accumulate a cloudy layer. And with double glass, you just can't get in and clean it without disassembling it. And let's not even describe the times that it became the fashion in a nearby hive of paperwasps or something, to crawl inside, get stuck in there, and desiccate one's little body as an
art exhibit for posterity. Bleah!