Hard to say without a little more information, but I think No.
Where were they found? ( region, climate, country, state, etc.)
What were they growing on (tree species)?
What color is the spore print?
The most obvious give away for a psilocybin containing mushroom is flesh that stains blue when bruised. Many also have a ring around the stem, and a purple-black spore print.
If you have little knowledge or
experience picking wild mushrooms, I certainly wouldn't start with that.
Buy and read a mushroom guide book before eating anything wild, and then stick to the fool-proof fungi until you gain a lot of experience or work with an experienced mushroom hunter or mycologist .
Stay safe!