Welcome to Permies, Ross! A
rocket mass heater can be a good way to warm a
greenhouse, and using an interior wall as the thermal mass could work fine.
I have some questions about your proposal, though. Is it an existing
wood stove you show for the firebox? Wood stoves (unless they are very modern high efficiency ones) will not burn well
enough to use as part of a
rocket mass heater. Only a refractory lined chamber can stand the high temperatures needed, and a wood stove sheds too much heat to work. The firebox needs to be built into the wall or an extension of it. Connecting the firebox to the wall with a stovepipe will not work, and you will not get any secondary burn in the wall cavity. It will just cool the smoke and condense creosote in the passages.
Presuming you want a heater that does not need to be fed every half hour or so, you would want a batch box combustion core. You can find all the information you need to do that properly at
batchrocket.eu.
Setting the batch box core into a cavity in the wall would work well, and the most effective as well as easiest way would be to make it a double wall with around an 8" space between the sides, and the exit to the chimney from the bottom of the cavity. A bulge in the wall cavity to give room for the combustion core with heat riser will hold all the workings.