Neat idea, I love building methods that can be done incrementally.
To minimize the number of molds needed and the side of the pieces, maybe try this kind of dome:
https://www.domerama.com/calculators/trapezium/
This is like the orange slices.
To figure the dimensions of a block rather than a flat panel, calculate an inner and an outer dome and the distance between the two.
I think styrofoam blocks skinned in netting and plastered with cement could be a good option.
Concrete made with Styrofoam could also be good:
https://permies.com/t/271989/Good-yt-video-increase-knowledge
Adobe blocks are free, but they do requires attention to detail that I myself don't think I could mister
Cast soilcrete blocks might be the best option in terms of materials required vs skill level.