We use a heat exchanger in our woodstove to heat a tank of water that has the well supply line coiled inside. It works great but will not heat anything when someone is not home for an extended period.
A reverse cycle chiller is a great device that can make gobs of hot water, ac and dehumidification happen at a c.o.p. of at least 2 to 6. They are available in pv direct-drive and operate to very low outdoor temps now.
The dirty secret of many off grid homes is propane but it can be an improvement over having utility supplied gas, and may be required in areas with low access to biomass,
which brings me to bio-diesel furnaces and boilers as a non petrol source. This can be done in many areas.
I like to utilize electricity for as much work as possible because the "fuel" is free and is transported free when available, and then we make up the rest with wood heat.
Automatic pellet fed boilers.
http://www.pellergy.com/wood-pellet-boilers/
Farm size!
http://www.maineenergysystems.com/autopellet-boiler-energy-box/
Here is a hybrid propane/solar combo water heater, it is pv direct, no batteries. It would work automatically.
http://www.sunbandit.us/