I went down the youtube rabbit hole the other day, after watching the videos linked in the "repairing hand tools" thread. I came across the technique of "japanning".
It is not, apparently, anything to do with japan. It was a European technique to imitate the black lacquered items coming from japan, and is unrelated to the Japanese methods.
Various recipes were used, but the are basically
Powdered bitumen/asphaltum
Linseed oil
Turpentine
It is mixed thoroughly and allowed to stand for 24 hours or so to thicken to a paint like consistency. Painted on to metal work, which is then baked.
Baking is a series of incrementally hotter stages, allowing to fully cool between steps, starting from about 200f for an hour, then stepping up to 250f, 300f, 350f, 400f - each held for an hour and allowed to cool between stages. In the curing process the turpentine and the bitumen power forms chemical bonds, essentially polymerising like a tough plastic. The oil adds flexibility so that the finished product doesn't end up cracking.
I love the look of the finish it produces.