I didn't have much luck planting rhubarb into grass, so you might have to mulch it well to get it established. I'm trying something similar with comfrey around some of my growing areas, against grass rather than deer though.
Rhubarb (Rheum rhabarbarum) is one of the plants; deer do not like to eat due to its high levels of oxalic acid. It is equally possible its pungent smells, and textured leaves are also other reasons while deer tend to stay away from them.
from
Natures mace
However, they go on to say deer will eat it if they are hungry
enough, and of
course there will be no barrier in winter when the plants are dormant. I think it could be an interesting experiment and makes me want to plant more rhubarb myself!