I heat with wood also and end up with a fair amount of ash. Here is what I do with it, some usage has already been mentioned above.
Perfect for cleaning the glass in front of the stove. Damp cloth dipped in a bit of ash, rub, rinse and dry.
I use it as a scouring pad. I clean all pots and pans with it - small amount of ash, a bit of water and a cloth or bare hands, rinse and dry
Laundry detergent. Equal amount of ash and cold water, mix, filter. Use as normal detergent
Dust bath for chickens
Into the
compost
Around the fruit
trees
On icy paths
In cooking, as mentioned above for baking but also a pinch of ash will help to cook pulses faster
I am sure there are more ways but these are the few at the top of my head.
I have found that ash does not work with slugs for me. I believe that it was the sharp clinker from coal burning that was a deterrent more than the ash itself.