if you like kimchi, there is a great kimchi made with garlic chives, i don't see why you couldn't do it with green onion leaves.
https://www.maangchi.com/recipe/pa-kimchi
I don't know about pickling, in my experience they get slimy.
My mother-in-law does what Megan says, harvests all her onions at once and slices up the leaves into rings or maybe 1-cm segments and freezes them loosely (laid out flat and then put in a bag) so she can use them over time. She usually has a quart sized container in the fridge with unfrozen ones too (they need to be absolutely dry or they will go bad, you can slice them and then lay them out in a tray for a little bit).