Bob,
Sorry about the nomenclature. To be honest, I did make up that abbreviation as I was going to simplify for readers, but apparently it complicated for you. So for the future, I will use MSFR to reference fast spectrum MSRs.
Just to expand for others, I think the point you were wondering about was xenon 135. Xe135 is something of a troublemaker in a moderated or thermal spectrum reactor. Xe135 is a very common by product of fission reactors, and Xe 135 just loves to suck up a stray neutron. In fact, in thermal spectrum reactors, Xe135 has such a propensity to eat up neutrons that it can actually shut down a reactor. This phenomenon is called xenon poisoning and was actually a contributing factor to the Chernobyl disaster.
In a regular, solid fueled moderated reactor, Xe135 is a real problem. It is a short lived element as it will decay with a 9 hour half-life, but during that time it will drastically lower reactor output unless more neutrons are brought to the party (which will then produce more Xe135). Modern reactors try to run as close as possible to a steady state in order to keep Xe135 manageable. In reactors used for submarines, where output can change drastically over short time spans, the Navy partially gets around this issue by having highly enriched uranium to always have even more neutrons to bring to the party in an emergency.
In a MSR, since the core is a liquid, when Xe135 forms, being a gas it simply bubbles out of the fuel and is pulled over offsite for some time to decay at which point the fission products are flushed back into the reactor to add to the fuel supply.
In a fast spectrum reactor, this step is not necessary. In fast fission, the neutrons are moving so fast that they produce fission almost every time they strike another fertile nucleus whereas with thermal fission, about 1/3 of the time (depends widely based on the exact element) the slowed neutron strikes the nucleus and bonds on, making a new element. In the case of Xenon 135, in the thermal spectrum, the neutron sticks and bonds almost 100% of the time. In fast fission, the neutron causes a fission event almost 100% of the time, meaning the trouble-making Xe135 is just another element to cleave in half and not a neutron sponge with a half-life of 9 hours. Also, because of fast fission’s tendency to always cause a fission event, a fast spectrum reactor has almost no potential to make any plutonium or other extremely long lived waste components. The fast fission cleaves them all up into smaller elements, almost completely eliminating the whole trans-uranics (TU)
class of waste and significantly reducing the quantity of fission product (FP) waste.
So why not make all reactors fast fission reactors? These sound great at first—nuclear energy with a mere pittance the nuclear waste. The main trouble historically has been cooling the (which is also how you remove the heat to do something useful like generate electricity). Fast fission (FF) coolant must be almost completely transparent to neutrons and not moderate them at all. That means you can’t use water as the hydrogen atoms in the water are pretty awesome moderators.
Historically the most commonly used FF coolant was liquid sodium which melts just above room temperature, or NaK, a eutectic of sodium and potassium that melts below room temperature. Actually, either of these make pretty awesome coolants. They melt low (so they don’t freeze in the heat exchangers—that’s bad), are very heat conductive, boil at high temperature so they carry a LOT of heat and are indifferent to neutrons (almost). So far they sound like great coolants. But anyone who has taken high school chemistry knows that sodium and potassium are wickedly chemically reactive (spectacularly in water) and to
boot are fairly corrosive in most metals. This is not to say that they can’t be used, they have, but the reactor itself needs a fair amount of maintenance. Another benefit (sarcasm here), you can find your coolant leaks quite easily!
Another FF coolant is lead or lead-bismuth eutectic (expensive stuff here). It also does not care about neutrons, carries a LOT of heat, and does not react like sodium. The Russians used a lead cooled FF reactor for their Alfa class submarine, a sub known for being very small and very, very fast. Another plus for lead coolant, you can actually get away with less shielding because the coolant IS shielding.
So what happened to these subs? The Soviets had a series of nuclear meltdowns from an ironic cause—they surfaced their submarines through Arctic ice pack into air that was more than-20F. The lead froze in the heat exchanger and plugged it up. The reactors overheated and partially melted down because they could not circulate the lead coolant. Ouch. Ironic—they melted down because they froze!
This is not to say that FF is inherently bad. In MSFR, the mechanics are entirely different. In an overheating situation, there is room at the top (in some designs a little pipe that extends up) for overheating salt to expand. Expanding salt reduces the fissile mass in the reaction chamber and fission reduces. In extreme events, the freeze plug melts at the bottom of the reactor and the fuel drains out.
FF reactors have two big but not insurmountable strikes against them. Firstly, FF needs a much larger fuel load. Secondly, we just have so much
experience with moderated/thermal fission that we know how it behaves. We have built two thermal MSRs, but no MSFRs. The potential is there, but it is just more of an unknown.
I hope this helps a bit and thanks again for everyone being so civil. It really makes this a great place to exchange ideas.
Eric