My favorite way to cut angles on straight cut piece of
wood is to use a pencil, knife and Japanese double sided pull saw. Draw the perfect 45' angle on the horizontal surface using a sharp pencil from the outside corner on both sides of the wood. Draw the perfect 90' angle on the vertical side of the wood and make sure this line meets both 45' inside angles.
Next, take a short, razor sharp carving knife (1 inch long blade) and cut the pencil line about 3/16" deep by hand on all sides (the outer corner is challenging and optional). Now switch from the knife to a super thin, double sided Japanese pull saw. Work the small teeth side into the thin groove, guiding the blade with your left thumb. Cut the inside and outside corners first so the blade can rock slightly as you proceed. Once you slowly perfect the line with the thin saw, the groove serves the same purpose as the miter box and holds the blade steady so you can cut the line exactly by hand. Switch to the larger teeth on the pull saw once you see that the line is straight and deep
enough to hold the saw steady without your left thumb guiding the blade.
This groove is thinner than the opening on the miter box and the saw is much more stable while cutting. I also find it easier to clamp the wood without the miter box.