i actually think this is a good idea, and yes i think it would work for what you are trying to do, though yes as you said it will me an epic months long, maybe year long process. but still it will help, i think its worth it.
one thing you could look into is Terra Preta -->
link for keyword terra preta
because it seems like this is basically what you are wanting to do. only this is generally made in a pit, you could do it in place, and further leave the mulch there and burn the mulch too.
the easy lazy way is to just burn a huge fire with scrap clippings and branches and random wood, keep adding "compost" more leaves and food waste and things that have some moisture, and then once it is going really well and starting to die down...pour a large amount of soil, screened native soil, or any other soil you want to sterilize some.
you can also sterilize your soil ...and solarization as mentioned above would also be something to try...but i like your idea of making terra preta in place. you would not need to remove the mulch unless you wanted too.
also maybe dont have to be that concerned about microorganism and such, yes it does set them back, but the land around it will just come back in and recolonize it as time goes by....but it does help to add fertility/finished composts/fresh mulch/compost tea or etc...at the very end to help that process.