Hello, fellow fans of
burning stuff to make it useful!
This is meant to be a comprehensive guide to to Charcoal, Activated Charcoal,
Biochar, what it all means and how to make it.
Charcoal vs Coal vs Charcoal Briquettes vs Lump Charcoal, what’s the difference?
Charcoal is the result of burning carbon-rich vegetable matter in a high temperature
and low oxygen environment. Good charcoal is almost entirely pure
carbon.
Coal: A combustable black or brown lump material that is mined from the ground. This coal is mostly carbon, along with various other elements like sulfur, nitrogen, and hydrogen. Coal is formed when dead plant matter decays into peat and is converted into coal over millions of years inside the earth’s crust. Coal burns very hot and is often used in metallurgy (though chemical transference from coal into the metal is a risk), but its use and extraction is extremely damaging both to human health and the environment at large.
Charcoal Briquettes: This is made from a combination of several materials. Generally,
wood particles, sawdust, and chemical additives like limestone, starch, sodium nitrate, paraffin wax, and
petroleum solvents. These all help with ignition, binding ingredients together, and artificially whitening the
ash left behind. Match-Light or Instant-light varieties of Charcoal Briquettes may also have a hydrocarbon sprayed on the surface to encourage quick ignition. If you’re trying to be organic or ‘permaculture’, this is not what you want.
There ARE some options for “natural” briquettes that use hardwood sawdust and cornstarch as a binder. You gotta read the ingredients list & pay attention to what’s inside.
Briquettes are generally square, rectangular, spherical, cylinder or pillow-shaped.
Pure Wood Charcoal, also called
Lump Charcoal: This is just chunks of plant material that has been made into charcoal through heating. The wood is unprocessed (not sawdust, no binders). It’s normally more expensive than Briquettes, but you can make your own pretty easily, through the methods described below.
For the rest of this post, I will be using the word “Charcoal’ to specifically mean ‘Plant-based Charcoal’
Burning Wood vs Making Charcoal
While burning wood in a regular well-ventilated campfire, oxygen enters and oxidizes the carbon, turning it into ash. Ash is primarily
oxidized carbon.
At high temperatures, violate compounds such as
water, methane, and other molecules are also oxidized (broken down), or are evaporated out. In general, an organic molecule will break down & oxidize (burn) at a lower temperature than pure carbon.
Even heavy metals begin to vaporize & become airborne at temperatures where charring occurs, so if you know you’re dealing with material that has been treated with lead, cadmium, mercury, etc, please DO NOT breathe in the smoke of vapors of that fire. Many substances have a vaporization point (becoming airborne in vapors) at a much lower temperature than its true boiling/evaporation point. (Where the material itself turns from a liquid to a gas.)
So, if you want to make CHARCOAL instead of ASH, you just need to take plant matter, limit the amount of oxygen that can touch it while hot, and get strong fire going around it for about a half-hour.
While it's experiencing high temperatures and low airflow, the carbon doesn’t oxidize. It doesn’t turn to ash. You still want to allow a little bit of air to escape, so those expanding gas compounds of non-carbon material wiggling free of their bonds due to the heat can get out as smoke and steam. (And not explode your container)
Charcoal can be made by making a pile of plant matter and covering it with a layer of dirt before igniting.
It can be made in a specialty kiln.
It can be made by placing a metal barrel of wood (with a few holes punched in it) inside a bonfire.
It can be made by putting wood inside a metal lidded pot, and put inside a small campfire.
Charcoal can be made with any carbon-rich plant material. All of these materials can be made into charcoal via the methods described above:
Hardwood or Softwood split logs, dry pine needles, pinecones, seed husks, branches, twigs, shavings, woody vines, reeds, raspberry canes, dried stems, dried leaves, corn husks, dried corn cobs, coconut shells, dried grass clippings, dried moss, peat, dried palm leaves, quite literally
any plant that is considered ‘brown’ for the sake of composting can also be made into charcoal.
(Note: please don’t burn or char poison ivy, poison oak, or other obviously-poisonous plants. Just like heavy metal and herbicides can become airborne with heating, so can the rash-causing compounds. You don’t want to breathe in aerosolized Urushiol (the chemical in poison ivy that gives you a horrible rash can also be carried & affect you through the smoke & vapors).
Heat required to turn plant matter into charcoal
In Feurdean’s experiments on charcoal production and the effect temperature had on biomass loss during charring; Leaves, sphagnum moss, and tree trunk wood produced the lowest amounts of charcoal per unit biomass during charring, and lost their mass more rapidly with increasing temperatures. Leaves of heathland shrubs, forbs, and ferns, as well as fern stems with leaves produced the most charcoal per unit biomass, and retained the greatest mass at higher temperatures.
Fuels rich in cellulose and hemicellulose, like leaves and ferns, were able to turn to charcoal at lower temperatures on average, BUT had a narrow temperature range before turning to ash. (200-400 degrees Celsius / 400-750 degrees F)
Fuels rich in lignin (like wood), turned to charcoal at a wider range of temperatures. (160-900 degrees C / 320-1,650 degrees F)
So, if you want to turn non-wood plant matter into charcoal, you'll want lower temperatures & careful temperature control - while wood charring is far less fussy.
Source: Experimental production of charcoal morphologies to discriminate fuel source and fire type, by Angelica Feurdean from the Department of Physical Geography, Goethe University, Germany. (Revised January 2021)
Because of the low temperatures required for grass & leaves to turn to charcoal, and the ease of acquiring those things throughout the year, it could be an attractive source of charcoal to create biochar for a home gardener, or otherwise a useful way to put huge piles of dropped leaves to use.
It can also be a reliable source of charcoal for crushing & turning into your own custom briquettes, by adding a binder. (You can mix flour & water with crushed charcoal to make a thick paste, then put into a mold or an egg carton to make DIY briquettes.)
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What about Biochar?
There are two commonly-used definitions of 'Biochar'.
The first, used by many
gardening folks & seen here on Permies, is 'Charcoal that has already been inoculated with nutrients, so that as it breaks down in the soil it acts as an organic slow-release fertilizer.' This can be made by dumping charcoal into
compost bins, into compost tea, or mixing it with manure.
Basically, treating charcoal or activated charcoal as a molecular pantry.
You 'Charge' it, or 'Stock' it, and turn it into biochar by soaking charcoal in nutrients that microflora crave. Those molocules adhere to the porous surface of the charcoal, until the charcoal breaks down.
This stockpiles nutrients in a place that won't rinse away as easily as free-floating molecules would.
The Other Definition
The other definition... actually means exactly the same thing, but approaches it from the opposite direction.
Instead of "Charcoal or Activated Charcoal that is inoculated for use in soil amendment" being the definition, professional biosystems engineers, and plant & soil scientists separate Biochar from regular Charcoal by 'Intended use' and 'material origin'- that is, because the charcoal is intended to be used as a soil amendment AND it is purely carbonated plant matter, it is biochar.
Wood Lump Charcoal, Charcoal made from coconut husks or other plant matter, and Biochar are all carbon-rich solids from plants that are put through pyrolysis. Chemically, physically, they are the same.
The main difference is LINGUISTIC.
Most people think of wood-based charcoals when you say 'Charcoal', and 'Biochar' more broadly includes other plant matter.
Additionally, 'Charcoal' colloquially includes items like charcoal briquettes, which may have petroleum additives and are not appropriate for soil remediation.
So, the difference between 'Biochar' and 'Charcoal' is not a chemical one, but rather a language choice for clarification & specification: Biochar is purely carbonized plant matter (charcoal), which is intended to be used in soil remediation.
Biochar is NOT charcoal briquettes, or any other charcoal-based product which includes processed fillers or synthetic additives.
This version of 'Biochar' does not imply that nutrient inoculation has already been performed, only that it is intended to be used for that in the future.
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What about Activated Charcoal?
Activated charcoal is to Charcoal is like popped popcorn is to corn kernels. It’s more porous, ‘fluffier’, and has a larger surface area.
Activated carbon is a much more powerful molecular binder - while Charcoal is a magnetic pantry to hold onto molecules, Activated Charcoal is more like a supermagnet with an attached garage. It is more aggressive about sucking up other molecules & has more storage space to keep them held.
Note: Charcoal and Activated Charcoal/Activated Carbon ADsorbs things. It doesn’t ABsorb things.
When something is ADsorbed, particles stick to the surface due to molecular forces like positive/negative charges. A magnet ADsorbs iron particles.
When something is ABsorbed, the particles are soaked into the matrix of the material. A sponge ABsorbs water.
How to Activate Charcoal
Activated Charcoal (also called Activated Carbon) is made by EITHER heating charcoal in temperatures exceeding 600 degrees C (1,100 degrees F) while in a no-oxygen environment (This requires using a special chamber where you can heat up your charcoal in the presence of something like Argon instead of a regular mix of air to prevent any oxidation), OR crushing normal charcoal to a powder, adding an strong acid, strong base, or salt, then heating it again to temps between 250-600 C (400 - 1,100 F) <-- much more accessible!
Recipe for activating charcoal:
> Pickle Crisp - Calcium Chloride - a type of salt. You can buy it in big tubs at most places that
sell pickling materials.
> Water
> Charcoal
Step 1: Make charcoal. Then powder charcoal by smashing with a hammer or using mortar and pestle.
Step 2: Be careful, this step generates heat. In a STAINLESS STEEL (not aluminum) bowl; Make a 25% solution of calcium chloride with water, at a 1:3 ratio.
If you have 600 ml of water you want 200 grams of calcium chloride. You want to make
enough of the solution to completely cover the powdered charcoal.
Using tapwater is fine, because the amount of trace minerals in tapwater is basically nothing compared to how much the carbon can adsorb.
Step 3: Add your solution to your powdered carbon, a little bit at a time. You may not use all of your solution - once it reaches a thick paste consistency (like peanut butter), stop adding more solution and just mix the paste until smooth. Get out all the lumps.
Step 4: Cover the bowl with a towel and let it sit untouched for 24 hours to allow the chemical reaction to continue.
Step 5: Drain off the liquid using a
coffee filter or very fine muslin cloth. Put the sludge back into your metal pot.
Step 6: Take your pot of nearly-activated-carbon, put the lid back on, and put it into a fire that exceeds 200 degrees C (400 degrees F) - a normal campfire
should do the trick. Keep it on the fire with the lid on until it stops steaming, and then take it off to let it cool - don't open the lid until it's completely cool.
Congrats, you’ve activated your charcoal!
WARNING:
When ingested, Charcoal and Activated Charcoal will ALSO bind to medicines in your gut, along with helpful vitamins, minerals, and antioxidants from our food instead of letting the body absorb it. Our bowels pass the charcoal much faster than the charcoal takes to release those nutrients and medicines back to us.
DO NOT ingest activated charcoal within 48 hours of taking, or expecting to take, any type of necessary medicine. Especially antidepressants and anti-inflammatory medications. The charcoal will likely deactivate & adsorb it - or at the very least make it less effective than that dose should be.
Charcoal and Activated Charcoal is not absorbed by the bloodstream. It stays in the digestive tract until excreted via bowel movement. This means it has no ability to remove alcohol from the bloodstream.
Well, under what circumstances CAN I use charcoal on people or animals?
Medicinally, orally, to treat acute poisoning or food poisoning (they ate something poisonous or spoiled: NOT envenomation. Charcoal won’t stop a spider or snakebite)
Medicinally, orally, to treat some types of parasitic worms.
Medicinally, orally, to relieve symptoms of bacterial infection in the gut, by absorbing bacterial-secreted toxins. (Does not kill the bacteria itself, but can help the body fight those bacteria by adsorbing their main weapon. Activated carbon has no significant influence on the microflora content of the gut biome - it does not kill bacteria when ingested)
Decoratively, as a powder or paint application to the skin.
As of July 2022, there are no
scientific studies that support the use of charcoal or activated charcoal in facial care, beyond its exfoliant (rough texture) properties.
Its ability to ‘remove toxins’ has been studied several times, and there is currently no evidence to support that property when used in topical skin creams.
There are also no published studies that support the use of charcoal in whitening teeth. (But there is evidence to show that the black powder can settle into tiny cracks and pores in the enamel and darken the tooth)
Charcoal is not a cure-all. It can't cure or clear the effects of acid, iron overdose, lithium, alkali, alcohol, or chemicals from gasoline.
For some people who are more sensitive to it, or if you take a very large dose in a very short time, charcoal can cause vomiting & constipation. While there is no 'toxicity', you can have adverse effects from administering it. (In the same way a glass marble is not poisonous, but if you eat several marbles your gut may feel uncomfortable until they pass out the other end)
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Other Uses for charcoal
Activated Charcoal filtering chlorine, heavy metals, and other substances from tap water.
Whole charcoal sticks can be used as a writing utensil.
Powder-ground charcoal + Drying Oil (like linseed) = Black oil paint.
Powder-ground charcoal + water + Vinegar = Black Ink (For use in calligraphy or watercolor. Shape before using)
Powder-ground charcoal + sulfur + saltpeter = Black Powder
Charcoal + compost/nutrients/compost tea/urine =
Biochar. ← if you want your biochar to be able to hold way more nutrients, then use activated charcoal instead of normal charcoal.
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Note on Calcium Chloride regarding its use in organic farming & activating charcoal:
You can extract Calcium Chloride by applying hydrochloric Acid to Limestone.
Stomach acid (found in mammalian stomachs) is hydrochloric acid. Hydrochloric acid is also naturally occurring around volcanoes and hot springs, as a result of hydrogen chlorine gas dissolving into water. So, it's also possible to find naturally-occurring Calcium Chloride where volcanic-produced hydrochloric acid meets limestone.
Calcium Chloride is commonly used in canning foods to keep them crunchy, as an electrolyte in sports drinks and bottled water, and in cheesemaking to restore the balance between calcium and casein protein. It is used in marine aquariums as a bioavailable calcium supplement for carbonite-shelled animals like mollusks.
However, major manufacturers of Calcium Chloride use several different synthetic chemicals manufacture it en-masse. Because of this, NOSB voted to allow Calcium Chloride ONLY if natural food-grade sources are used, OR it is used specifically as a foliar spray at minimum levels to treat calcium deficiencies.
Since I am recommending using food-grade sources, and only small amounts are used, this should be in accordance with NOSB guidelines.
(Source: National Organic Standards Board Technical Advisory Panel Review from 2001, page 2)