I tried rust dying about 10 years ago, when I first heard of it. It can be lots of fun, and I love the suggestion of adding tannins to the mix.
I dyed both cotton and silk. Both took the color without mordant… though iron is used as a mordant, so perhaps my statement is not accurate. I
should say without additional mordant, which leads me to possibilities I did not investigate, such as adding various mordants to the process, alum, chrome, tin etc. If tannins get you into the bluish realm, what else might be awaiting us?
One thing I discovered that might be good to know, it changes the hand of the dyed fabric. The light weight silk was stiffened, and so was everything else, but being so light and soft, it was most noticeable on the silk.
Of
course I made up a story for myself, about what could explain the phenomenon! I think the iron itself, a large and heavy atom? ion? molecule? attaches itself to the fiber, the amount depending on how dark you dye it. And how can that not make the formerly light and “fluffy” fibers of the textile stiffer, heavier, scratchier?
All the same, it’s a wonderful process to experiment with!