My favorite mulch material tends to be whatever biodegradable material I can get in abundance, for free. Typically that's wood chips, as the
local arborist company drops loads my front pasture whenever they get a job in the area, and I also have a friend who does landscaping/property clean-up and occasionally has to chip trees/brush in her job. This has taught me that wood chips come in many different forms, but my favorite is when the mulch is finely chipped branches that were full of leaves when ran through the chipper. It comes out soft & fluffy, which is perfect for layering deep on my gardens/beds.
Leaves are great, as well. Prior to my great grandparents buying the
land in the 1950's, the property was part of a big pecan orchard, so we have 8 mature pecan trees that are about a hundred years old and drop a ton of leaves each fall. Since raking takes too much time with the days being so short, I usually just rake them into the ornamental beds around the house and also try to give each pecan tree about a foot of leaves from the trunk to dripline to help nourish them for the next year (they're getting old for pecan trees, so I tend to baby them).
My show
rabbits produce about a ton of manure each year, and much of that is used as a mulch/top dressing when it's not needed for another
project.
Like Eric, I also work in the education field, and shred anything confidential to use in worm bins & as mulch.
It's always interesting to learn what others use, based on the materials they have easy access to. I would have never thought of using seaweed/kelp as a mulching material since that's something I rarely see.