So Carpenter Brothers did get back to me about their riser sleeves. They offer two, both intended as disposable forms for metal casting.
The LD Riser Sleeve in 6" interior diameter was $5.20 each, minimum order a carton of 18.
Its composition:
COMPONENT WT% CAS NO.
Aluminosilicate 20-30% 142844-00-6
Silica quartz 50-60% 14808-60-7
Free silica 0-0.1% 14808-60-7
Calcined kaolin 0-5 % mixture
Iron oxide 0-1 % 1317-61-9
hexamethylenetetramine 0-1% 1344-28-1
That seems like an awful lot of sand to do much insulating.
The materials SDS also did include a number of dire toxicity warnings, including cristabolite, but of which the most concerning was an order to "Keep away from heat/ sparks/ open flames/ hot surfaces" and further notes that it released all manner of dangerous gasses during combustion, including fluoride, generated extremely high temperatures, and could not be extinguished with
water but only sand. This does not sound good for our application. When I asked the sales rep about this, his reply was:
" I don’t know why it says that. The only thing that would make sense to me is that they just copied the SDS from the exothermic riser sleeves for the insulating riser sleeves and didn’t realize it or no one ever mentioned it. "
Anyway, he then added that the higher quality, more insulating one would probably work better for our uses. Haven't got a price on that but I'm guessing it would be more in line with High Temp Inc.'s offering of $12 each/ minimum order of 30. The composition of these:
"Aluminosilicate Refractory Ceramic Fiber 61-71%
Crystalline Silica (Quartz) 12%
Colloidal Silica 4-7%
Modified Starch 4%
*Note: Rigidizing is a secondary operation that will ultimately affect the concentration of colloidal silica in the final product. The concentrations listed above reflect that of a product prior to rigidizing; post-rigidizing concentrations vary from product to product."
For this more insulating sleeve, he then sent me the SDS for Morgan Cerablanket, classification 2300*F, which we have probably all seen before. Plus the following note on temperature classification for both products:
"But riser sleeve manufacturers do not list these working temperatures because the riser sleeves are designed as a one-time use in a mold and will burn up, but the sand mold surrounding the riser sleeve prevents the metal from running out if the sleeve burns up."
So ... if I am understanding him correctly, it is essentially a 1/2" thickness 5 minute riser soaked in fumed silica, with a little bit of sand. Only you have to buy a whole carton at once.
I still feel like there have to be some kind of magic words I'm failing to say to get them to understand what I'm after: rigid, sturdy, insulating, long lasting, high temperature use without the binders giving way, resistant to flux and
wood gas attack, not too poisonous. In other words, the aforementioned "sexy beast to beat!" But searching "Ceramic chimney liner," which seems to be what Peter calls it over in the EU, just gets me to terracotta, and adding "refractory" to the search terms only turns up an alumina cement coating for old terracotta, while "ceramic fiber chimney liner" gets me to the right product ... in China. The Vacuduct people, who do seem to be making exactly what we're after, when contacted pulled the same game most of the rest of these companies have done: I asked them what they had and what the minimum order might be, but they turned it around and said they just couldn't
answer that until I told them what they had and what the minimum order would be. (??! So frustrating. Carpenter Brothers and High Temp Inc do at least get credit for not pulling that nonsense!)
... So that's as far as I've gotten.